dse Chem lithium ion rechargeable cell

33 回覆
1 Like 6 Dislike
2016-12-07 21:43:18
Electrolye 係一舊lithium salt in organic solvent

請問點解係organic solvent內,都會出現
Li <> Li^+ e-
CoO2 + e- <> CoO2^-
2016-12-07 21:44:37
有乜問題
2016-12-07 21:45:12
2016-12-07 21:46:34
有乜問題


正常redox如果以electrochemical series predict feasibility
條件要係aq

但而家係organic solvent, 想知點解都可以有redox
2016-12-07 21:47:31
點解organic solvent 唔可以有redox??
2016-12-07 21:50:02
點解organic solvent 唔可以有redox??


我無話唔得
只係想知點解姐

因為一路以來都係aq下用electrochemical series predict redox feasibility
我dse唔知organic solvent都可以有redox 姐...🙈
2016-12-07 21:53:27
你好似無正面答我問題😂
2016-12-07 21:57:22
你好似無正面答我問題😂


Why not 之後 ester ethene ... reaction好多係redox
唔記得D名 dse Chen
2016-12-07 21:59:40
你好似無正面答我問題😂


Why not 之後 ester ethene ... reaction好多係redox
唔記得D名 dse Chen


試下放隻手落mno4-
Release electron absorb electron= redox
2016-12-07 21:59:54
REDOX係可以以幾種形式表達
1. Change of charge
2. Change of hydrogen
3. Change of oxygen
4. Simply changing of oxidation number

Aqueous state 既 redox係比你參考個feasibility, 但唔代表係organic solvent唔可以有redox

例如燃燒hydrocarbon(如汽油)都係redox reaction 不過energy 唔係以電力electricity/electron形式去轉換能量
2016-12-07 22:04:58
REDOX係可以以幾種形式表達
1. Change of charge
2. Change of hydrogen
3. Change of oxygen
4. Simply changing of oxidation number

Aqueous state 既 redox係比你參考個feasibility, 但唔代表係organic solvent唔可以有redox

例如燃燒hydrocarbon(如汽油)都係redox reaction 不過energy 唔係以電力electricity/electron形式去轉換能量


其實有咩唔係redox 諗落好似冇
2016-12-07 22:08:55
REDOX係可以以幾種形式表達
1. Change of charge
2. Change of hydrogen
3. Change of oxygen
4. Simply changing of oxidation number

Aqueous state 既 redox係比你參考個feasibility, 但唔代表係organic solvent唔可以有redox

例如燃燒hydrocarbon(如汽油)都係redox reaction 不過energy 唔係以電力electricity/electron形式去轉換能量


其實有咩唔係redox 諗落好似冇


Precipitation
CaCl2 + 2NaOH => Ca(OH)2 + 2NaCl
2016-12-07 22:12:57
REDOX係可以以幾種形式表達
1. Change of charge
2. Change of hydrogen
3. Change of oxygen
4. Simply changing of oxidation number

Aqueous state 既 redox係比你參考個feasibility, 但唔代表係organic solvent唔可以有redox

例如燃燒hydrocarbon(如汽油)都係redox reaction 不過energy 唔係以電力electricity/electron形式去轉換能量


其實有咩唔係redox 諗落好似冇


Precipitation
CaCl2 + 2NaOH =&gt; Ca(OH)2 + 2NaCl


重有冇?
應該真係無我記得
2016-12-07 22:18:34
大佬呢個年代有google架喇喎
當年我無google先要記住姐
http://chemistry.stackexchange.com/questions/18492/is-there-non-redox-reaction

加油啦DSE雞們
2016-12-07 22:38:34
大佬呢個年代有google架喇喎
當年我無google先要記住姐
http://chemistry.stackexchange.com/questions/18492/is-there-non-redox-reaction

加油啦DSE雞們


Thanks

但唔同環境,個個feasibility 應該唔同?
即無organic solvent 內 feasibility (reduction potential)唔會同 aq時候一樣?
2016-12-07 22:41:01


This is dry ether, an organic solvent for redox reactions.

Note the oxygen atom. You can see that it has lone pair electron for transfer.


Thanks 🐢sir
我清左最重要concept 了!

重點係有e transfer -> redox
而點有e transfer , 真係睇唔同條件下既potential differences 了...
2016-12-07 22:42:50
大佬呢個年代有google架喇喎

當年我無google先要記住姐

http://chemistry.stackexchange.com/questions/18492/is-there-non-redox-reaction



加油啦DSE雞們




Thanks



但唔同環境,個個feasibility 應該唔同?

即無organic solvent 內 feasibility (reduction potential)唔會同 aq時候一樣?

aq 要睇埋 pH


Yes! I got this!
2016-12-07 22:54:39
大佬呢個年代有google架喇喎
當年我無google先要記住姐
http://chemistry.stackexchange.com/questions/18492/is-there-non-redox-reaction

加油啦DSE雞們


Thanks

但唔同環境,個個feasibility 應該唔同?
即無organic solvent 內 feasibility (reduction potential)唔會同 aq時候一樣?


觀念正確
2016-12-07 23:02:50
大佬呢個年代有google架喇喎
當年我無google先要記住姐
http://chemistry.stackexchange.com/questions/18492/is-there-non-redox-reaction

加油啦DSE雞們


Thanks

但唔同環境,個個feasibility 應該唔同?
即無organic solvent 內 feasibility (reduction potential)唔會同 aq時候一樣?


觀念正確


仲想問多題:corrosive property of a chemical

Dse 大概我知係
Acid / base/ alkaline metal / h2o2 / dehydrating agent

有個特別case:
AlCl3 佢都係corrosive
1. 如果我話因爲佢係acidic salt, concept上有無問題?
2. 如果無問題?是否所有acidic or alkaline salt都具有corrosive property?
2016-12-07 23:17:09
大佬呢個年代有google架喇喎

當年我無google先要記住姐

http://chemistry.stackexchange.com/questions/18492/is-there-non-redox-reaction



加油啦DSE雞們




Thanks



但唔同環境,個個feasibility 應該唔同?

即無organic solvent 內 feasibility (reduction potential)唔會同 aq時候一樣?




觀念正確




仲想問多題:corrosive property of a chemical



Dse 大概我知係

Acid / base/ alkaline metal / h2o2 / dehydrating agent



有個特別case:

AlCl3 佢都係corrosive

1. 如果我話因爲佢係acidic salt, concept上有無問題?

2. 如果無問題?是否所有acidic or alkaline salt都具有corrosive property?

AlCl3 + HCl ---&gt; H(AlCl4)

AlCl3 is actually not purely acidic.

Anyway, a dissolved chemical that can change pH from neutral is corrosive by definition.


了解des
2016-12-08 01:38:12
AlCl3 + HCl ---> H(AlCl4)
Hcl本身就acidic 喎

Alcl3 is a strong Lewis acid,
Which can react with water to form hydronium ion
[Al(H2O)6]3+ ⇌ [Al(OH)(H2O)5]2+ + H+
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