https://pubchem.ncbi.nlm.nih.gov/compound/MALONONITRILE#section=Fire-Hazard
10.1.3Fire Hazard
When heated to decomposition, malononitrile emits highly toxic fumes (cyanide). May polymerize violently on prolonged heating. Avoid heat. Hazardous polymerization may occur, at prolonged heating at 266F or contact with strong bases at lower temperatures. (EPA, 1998)
https://onlinelibrary.wiley.com/doi/10.1002/047084289X.rm015
Handling, Storage, and Precautions: caution:
highly toxic irritant and should be stored in a well‐ventilated fume hood.
Over time, colorless malononitrile becomes dark and eliminates hydrogen cyanide. Inhalation should be avoided. Persons who suffer from a poor sense of smell, heart condition, or blood circulation problems should not be exposed to malononitrile.
Above 100 °C, malononitrile may decompose spontaneously.